Yep, everybody knows that petrol is what fireman uses to extinguish a fire, they do that, don't let them cheat you telling is water...
This appears to be that you are doing one of two things:
1. Being purposely disingenuous by utilizing a strawman, or
2. You really do not understand.
Let me elaborate: I was a firefighter for over 20 years, the last 12 it was my profession. The "Hollywood" myth is that fuel explodes or even catches on fire easily, (or as you infer: spontaneously like batteries, especially lithium ion batteries, will do). It does not. It takes a lot of heat and an unvented vessel to cause the types of explosions seen on tv and in the movies.
Does it burn vigorously? Yes. Fuel is one of the most efficient means of combustion we use today, if not the most efficient. The reason for this efficiency is due to its ability to not only burn readily in proper conditions, but the amount of power derived from burning fuel.
Proper conditions is the watch word here: Normal unleaded gas does not readily ignite without the proper fuel-air mix, which is a very narrow window. Too much fuel or too much air prevents fuel from igniting. Proper containment, such as vented tanks and such, does not allow for combustion unless certain factors are in play: Containment has to be breached in one manner or another. Enough oxygen, but not too much, is introduced in such a manner that we get a proper fuel/oxygen ratio. A method of combustion must be introduced
at the right time and for the right amount of time (allowing for conditions), that will not only ignite the fuel but allow ignition to sustain for any period of time.
It is very rare that you get those conditions in normal driving or even when the car is parked or being re-fueled. Even sparks will not readily ignite fuel or cause it to explode unless those conditions are present.
Vehicle fires involving fuel are not from fuel spontaneously igniting and spreading, but from other parts of the vehicle igniting and the fuel system becoming involved. Yes, you can get fuel on a header and it can ignite, but that is not due to the volatility of the fuel but rather due to a mechanical malfunction that caused the fuel to ignite.
Diesel is even harder to burn.
You, again, infer that gasoline has a propensity to spontaneously ignite like batteries do. It does not. When I responded to vehicle fires I was not worried about the fuel, that was easy to handle, I worried about tires exploding (not too much danger but they are loud and tend to startle, try working next to a tire when it goes off. My ears rang for three days.) and batteries exploding. Those two parts of a vehicle were the ones that exploded the most. I never had a vehicle fire that could be directly attributed to fuel spontaneously igniting, nor did I ever have a vehicle vigorously combust (explode) due to fire or other influences.