the temperature calculation in pCars2 is quite complicated, when you start a race is like your entire rim+tire+brakes has been into an oven and pre-heated to a temperature that's optimal for the tire (like everything on 80°).
But then, when racing, the brake will get quite hotter than that, and so will do the rim and the air inside it, this will make the tire pressure grow (it stabilizes after 6-10 laps depending on the car). But also, depending on air and track temperature, your tire temperatures will vary.
The temperatures that the game simulates are
-brake core
-brake surface
-rim
-air inside the tire
-tire rubber core
-tire rubber surface
-tire thread (the thinnest surface that's actually in contact with tarmac and has his temperature growing/decreasing fast and's responsible for the changes of grip during cornering)
what you see in telemetry screen are brake surface (i think) and tire surface, you should aim to have the tires in the 65-85° range for soft and 75+ for hards, for the brake there was a post on the forum with the right temperatures during braking for most kinds of brakes. The other temps are what makes the temperatures take some laps to stabilize, they all start at same temperature as the tire.